The building and construction sector accounts for nearly 40% of global greenhouse gas emissions, with steel-framed buildings being a significant contributor due to high CO2 emissions during production. To mitigate this issue, integrating Cross-Laminated Timber (CLT) into structural systems has emerged as a sustainable alternative. CLT, known for its carbon sequestration properties, offers an environmentally friendly replacement for reinforced-concrete slabs, particularly when paired with steel structures to enhance material reuse and reduce lifecycle impacts. This study focuses on hybrid systems combining H-shaped steel beams and CLT floor panels connected using high-strength friction bolts. A four-point bending test, simulating a secondary beam, was conducted, demonstrating that the composite effect significantly enhances flexural stiffness and strength. Additionally, a simplified method for evaluating the flexural stiffness and yielding strength of these composite beams, based on material and joint properties, was shown to successfully evaluate the test results.