Exptl. work was carried out to suggest that a practical alternative to fractional distillation for separation of propylene from propane (an energy-intensive operation) is adsorption.The exptl. work includes equilibrium and kinetic adsorption data and initial adsorption, using isotherms for C3 adsorption on 3 mol.-sieve zeolites (4A, 5A, 13X), 2 pentasil zeolites, silica gel, and coconut-based activated carbon.Breakthrough data were provided for both adsorption and regeneration steps for activated carbon, silica gel, activated alumina, and the mol. sieves, which were considered superior to the other adsorbents for breakthrough separationsA flow diagram for the complete proposed process was included.Single-step adsorption cannot be utilized in propane-propylene separationA three-step adsorption process based on heavy dilution with an inert gas is an interesting option.Adsorption can also be combined with other separation methods in order to reduce the high energy consumption of distillationA hybrid process of adsorption and distillation was introduced.Finally, a propane-propylene membrane separation (using AgBF4/Nafion membrane) was discussed and a novel membrane structure was introduced and analyzed.